The paper reviews the results obtained with a Sievers-820 total organic carbon (TOC) analyzer during ground tests of the Mir water recovery system (WRS). Calibration analysis results for water solution samples of individual compounds, typical of spacecraft atmospheric humidity condensate, and their mixtures are provided. Comparison of the test results to the calculated data and laboratory analyses performed by other methods are made. Analyzer readings are in good agreement with the chemical analyses of initial condensate and recovered water. The analyzer shows promise as an instrument for ground and future onboard spacecraft testing.