Changes in exhaust gas emissions during starting in a DI diesel engine were investigated. The THC after starting increased until around the 50th cycle when the fuel deposited on the combustion chamber showed the maximum, and THC then decreased to reach a steady value after about 1000 cycles when the piston wall temperature became constant. The NOx showed an initial higher peak just after starting, and increased to a steady value after about 1000 cycles. Exhaust odor had a strong correlation with THC, and at the early stage odor was stronger than would be expected from the THC concentration. The THC increased with increased fuel injection amounts, decreased cranking speeds, and fuels with higher viscosity, higher 90% distillation temperature, and lower ignitability.