Quantitative LIF measurements of liquid fuel films on the piston of direct-injected gasoline engines are difficult to achieve because generally these films are thin and the signal strength is low. Additionally, interference from scattered laser light or background signal can be substantial. The selection of a suitable fluorescence tracer and excitation wavelength plays an important role in the success of such measurements. We have investigated the possibility of using toluene as a tracer for fuel film measurements and compare it to the use of 3-pentanone. The fuel film dynamics in a motored engine at different engine speeds, temperatures and in-cylinder swirl levels is characterized and discussed.