An ion current sensor is employed in a 4 cylinder production SI engine for combustion diagnosis during combustion process, knock, and low speed pre-ignition (LSPI) detection.The results show that the ion current peak value and ion current peak phase have strong correlation with the cylinder pressure and pressure peak phase respectively. The COV of ion current integral value is greater than the COV of IMEP at the same operating condition. Results show that the ion current signal is sensitive to different lambdas. Using ion current signal, the knock in any given cylinder can be detected. Importantly, the ion sensor successfully detected the low speed pre-ignition (LSPI) about more than 20 °CA before spark ignition.