In this paper, the effect of the oxygen addition on engine performance and exhaust emissions was investigated. The experimental study was carried out in a small single-cylinder PFI SI four-stroke engine. The addition of the 5% vol and 10% vol of oxygen was performed in the intake duct. Typical urban driving operating conditions were investigated. The engine emissions were characterized by means of gaseous analyzers and a smokemeter. Particle size distribution function was measured in the size range from 5.6 to 560 nm by means of an Engine Exhaust Particle Sizer (EEPS). An improvement in terms of engine power output, without BSFC penalty, and HC emissions with oxygen addition was observed at all the investigated operating conditions. On the other hand, NOx and PM emissions increase.