Piston temperature plays a major role in determining details of fuel spray vaporization, fuel film deposition and the resulting combustion in direct-injection engines. Due to different heat transfer properties that occur in optical and all-metal engines, it becomes an inevitable requirement to verify the piston temperatures in both engine configurations before carrying out optical engine studies. A novel Spot Infrared Temperature Estimations (SITE) technique was developed to estimate the piston window temperature in an optical engine. Chromium spots of 200 nm thickness were vacuum-arc deposited at different locations on a sapphire window. An infrared (IR) camera was used to record the intensity of radiation emitted by deposited spots. From a set of calibration experiments, a relation was established between the IR camera measurements of these spots and the surface temperature measured by a thermocouple. Transmissivity of the chromium spot was investigated by using different background media. The deviations between the thermocouple readings and estimated temperatures were noted to be within 10℃ for the working range of 75℃ to 180℃. This technique was demonstrated to estimate the optical piston temperature during engine operation at 1500 rpm and 2000 rpm. A piston warm-up strategy was developed for optical engine studies to attain metal engine steady state piston temperatures. The effect of piston warm-up on in-cylinder soot formation was studied using high-speed imaging.