Investigation of Small-Scale Unintended Releases of Hydrogen 2007-01-0432

Knowledge of the concentration field and flammability envelope from a small-scale hydrogen leak is an issue of importance for the safe use of hydrogen. A combined experimental and modeling program is being carried out by Sandia National Laboratories to characterize and predict the behavior of small-scale hydrogen releases. In contrast to the previous work performed by Sandia on large, momentum-dominated hydrogen leaks, these studies are focusing on small leaks in the Froude number range where both buoyant and inertial forces are important or, in the limit, where buoyancy dominates leak behavior. In the slow leak regime buoyant forces affect the trajectory and rate of air entrainment of the hydrogen jet leak and significant curvature can occur in the jet trajectory. Slow leaks may occur from leaky fittings or o-ring seals on hydrogen vehicles or other hydrogen-based systems where large amounts of pressure drop occur across the leak path. Low-pressure electrolyzers or vents on buildings or storage facilities containing hydrogen are also potential sources for slow leaks.

The small-scale leak investigation is a combined experimental and modeling program. Comparisons are made between measured slow leak concentration fields and predictions from a first-principles slow-leak engineering model. Calculations from the model and experimental results are presented to explain the behavior of hydrogen slow leaks over the Froude number range of interest.