Search Results

The effect of the chemical reactivity of diesel fuel on PM formation was investigated using a flow reactor and a shock tube. Reaction products from the flow-reactor pyrolysis of the three diesel fuels used for the engine tests in Part 1(1) (“Base”, “Improved” and Swedish “Class-1”) were analyzed by gas chromatography. At 850C, Swedish “Class-1” fuel was found to produce the most PM precursors such as benzene and toluene among the three fuels, even though it contains very low amounts of aromatics. The chemical analyses described in Part 1 revealed that “Class-1” contains a large amount of branched and cyclic structures in the saturated hydrocarbon portion of the fuel. These results suggest that the presence of such branched and ring structures can increase exhaust PM emissions.

Methanol, gasoline and hydrogen are the primary fuel options under consideration for fuel cell vehicles (FCV). The ideal fuel would eliminate local air pollution, substantially reduce greenhouse gas emissions and oil imports, cost no more than current transportation fuels per mile driven, and require little investment in new infrastructure. In addition, the fuel used for future fuel cell vehicles should be suitable for near-term hybrid electric vehicles using internal combustion engines, to avoid the need for introducing more than one new motor fuel in the 21st century. All three primary FCV fuels have limitations: gasoline is the most difficult to reform to produce hydrogen and produces the least improvement in the environment and yields the least oil import reductions. Methanol is cleaner, easier to reform onboard the FCV, eliminates oil imports, but requires some new infrastructure.

According to the results of several studies concerning the influence of fuel formulation on exhaust emissions from diesel engines, a new matrix of twelve fuels was tested in a single cylinder DI diesel engine of conventional technology. The matrix was designed by the partners of the FLOLEV research project, partly founded by the E.U., in the framework JOULE III program. The aim of the project is to study the influence on pollutants emission reduction of modern refining process and fuel additivation with some alternative fuels and cetane improvers. The fuel matrix is structured into three sub-matrices. The first sub-matrix is constituted by six fuels which represent different products obtainable with the modern refinery technology. The second and third sub-matrices were designed to test the influence of cetane improver additives and high-oxygenated fuels respectively.

Combustion and exhaust emission characteristics were compared among three representative diesel fuels called “Base (corresponding to a Japanese market fuel)”, “Improved” and Swedish “Class-1” using both a modern small and an optically accessible single-cylinder DI diesel engines. In these tests, the relative amount of PM collected in the exhaust was “Base” >“Class-1” >“Improved” at almost all of the operating conditions. This means that “Class-1” generated more PM than “Improved”, even though “Class-1” has significantly lower distillation temperatures, aromatic content, sulfur, and density compared with “Improved”. There was little difference in combustion characteristics such as heat release rate pattern, mixture formation and flame development processes between these two fuels. However, it was found that “Class-1” contained more branches in the paraffin fraction and more naphthenes.

This paper investigates the combined effect of EGR and emulsified fuels on engine performance. The influence of intake air temperature (25∼86°C) on engine performance was examined prior to uncooled EGR experiments. Compared with gas oil, emulsified fuel gave simultaneous improvements in NOx concentration, smoke density, and specific fuel consumption (BSFC) over the tested range. The effect of EGR on engine performance were investigated with various water to fuel ratios at two load conditions (BMEP=0.52MPa and 0.26MPa). It was confirmed that at 11% EGR with the emulsified fuel at the rated output resulted in a significant reduction in NOx concentration without worsening smoke density and BSFC.

The engine selected for this work was a Caterpillar 3176 engine. Engine exhaust emissions, performance, and heat release rates were measured as functions of engine configuration, engine speed and load. Two engine configurations were used, a standard 1994 design and a 1994 configuration with EGR designed to achieve a NOx emissions level of 2.5 gm/hp-hr. Measurements were performed at 7 different steady-state, speed-load conditions on thirteen different test fuels. The fuel matrix was statistically designed to independently examine the effects of the targeted fuel properties. Cetane number was varied from 40 to 55, using both natural cetane number and cetane percent improver additives. Aromatic content ranged from 10 to 30 percent in two different forms, one in which the aromatics were predominantly mono-aromatic species and the other, where a significant fraction of the aromatics were either di- or tri-aromatics.

The Sasol Slurry Phase Distillate (SPD) process provides an opportunity to convert the world's abundant natural gas reserves into a conventional liquid fuel that is easily transportable and marketable. The high quality diesel produced by the Sasol SPD process could either be used on its own or as a blending component. Blending Sasol SPD diesel with crude oil derived diesel will improve the properties of the crude oil derived diesel so that it can meet the more stringent, environment and engine technology driven, diesel quality and emissions specifications. The properties of the Sasol SPD diesel and blends of Sasol SPD diesel and an on-highway, 2D-grade diesel fuel from the USA were compared to current and proposed specifications for high quality diesel which included CARB and Premium Diesel specifications from the USA. The compatibility of the Sasol SPD diesel with various elastomers was found to be similar to other low aromatic diesel fuels.

The U.S. Department of Energy (DOE) is embarking on a program investigating the use of Fischer-Tropsch (FT) fuels as a premium quality substitute or blending agent in direct-injection compression-ignition (diesel) engines. This paper aims to direct attention to the processing of FT fuels, emissions issues, available engine technology and the opportunity offered by FT diesel fuels for emissions control when considering diesel injection techniques. In modern automotive and heavy duty direct-injected (DI) diesel engines, precise fuel injection control is critical for achievement of 1998 and 2004 NOX and PM emission levels. High injection pressures, pilot injection and injection rate shaping are all optimized to maximize efficiency and power and to minimize emissions. These parameters must be considered as variables in the trade-off scenario between NOX and PM. Another parameter that may be considered important is the fuel type.

The effects of fuel properties of both oil-sands-derived and conventional-crude-oil-derived diesel fuels were investigated on a single-cylinder DI research engine. The engine used in this study incorporated features of contemporary medium- to heavy-duty diesel engines and was tuned to the U.S. EPA 1994 emission standards. The engine experiments were run using the AVL 8-mode steady-state simulation of the U.S. EPA heavy-duty transient test procedure. The experimental fuels included 12 fuels blended using refinery streams to have controlled total aromatic levels and 7 other diesel fuels obtained from different sources. The results showed that at a constant cetane number (44) and sulfur content (150 ppm), oil-sands-derived fuels produced similar NOx emissions as their conventional-crude-oil-derived counterparts and total aromatic content and fuel density could be used in a regression model to predict NOx emissions.

The diesel combustion process involves complex physical and chemical processes. Given this complexity it is not surprising that a wide range of fuel effects on emissions are reported in the literature. In the European Auto/Oil study the EPEFE programme showed that interactions between fuel and engine hardware could partially explain the observed emissions effects. Variations in fuel physical properties can lead to variations in injection timing, fuel delivery, exhaust gas recirculation (EGR) and other parameters. To understand fuel effects on emissions it is clear that we need to separate these different mechanisms. In this programme a modem, electronically controlled, direct-injection (DI) passenger car engine has been studied using a sophisticated test bed system which makes it possible to monitor and control all key engine variables. Seven fuels were tested, including four varying in density and poly-aromatics content taken from the EPEFE programme.

Sandia National Laboratories has been investigating a new, integrated approach to generating electricity with ultra low emissions and very high efficiency for low power (30 kW) applications such as hybrid vehicles and portable generators. Our approach utilizes a free piston in a double-ended cylinder. Combustion occurs alternately at each cylinder end, with intake/exhaust processes accomplished through a two stroke cycle. A linear alternator is mounted in the center section of the cylinder, serving to both generate useful electrical power and to control the compression ratio by varying the rate of electrical generation. Thus, a mechanically simple geometry results in an electronically controlled variable compression ratio configuration. The capability of the homogeneous charge compression ignition combustion process employed in this engine with regards to reduced emissions and improved thermal efficiency has been investigated using a rapid compression expansion machine.

Lower explosion limits (LEL) and the chemical compositions of JP-8, Jet A and JP-5 fuel vapors were determined in a sealed combustion vessel equipped with a spark igniter, a gas-sampling probe, and sensors to measure pressure rise and fuel temperature. Ignition was detected by pressure rise in the vessel. Pressure rises up to 60 psig were observed near the flash points of the test fuels. The fuel vapors in the vessel ignited from as much as 11°F below flash-point measurements. Detailed hydrocarbon speciation of the fuel vapors was performed using high-resolution gas chromatography. Over 300 hydrocarbons were detected in the vapors phase. The average molecular weight, hydrogen to carbon ratio, and LEL of the fuel vapors were determined from the concentration measurements. The jet fuel vapors had molecular weights ranging from 114 to 132, hydrogen to carbon ratios of approximately 1.93, and LELs comparable to pure hydrocarbons of similar molecular weight.

In his paper “The Knock Syndrome - its Cures and its Victims” (SAE 841339) Oppenheim proposed to change the whole process of the internal combustion engine replacing moving flames by homogeneous and simultaneous combustion. Intensive research work on flame propagation and auto-ignition phenomena led to new insights into combustion over recent years. The implementation of auto-ignition on two-stroke S.I. engines revealed the potential for simultaneous reductions in fuel consumption and NOx emission. Deploying the principle for the four-stroke piston engine and standard fuel would provide optimum conditions for application in common vehicles. The basic problem of homogeneous combustion is presented and some options of control are discussed. A methodology is proposed to apply a new type of combustion simply through a consistent combination of modern technology available for the S.I. engine.

The uniform lean gasoline-air mixture was provided to diesel engine and was ignited by direct diesel fuel injection. The mixing region that is formed by diesel fuel penetration and entrainment of ambient mixture is regarded as combustible turbulent jet. The ignition occurs in this region and the ambient lean mixture is burned by flame propagation. The lean mixture of air-fuel ratio between 150 and 35 could be ignited and burned by this ignition method. An increase of diesel fuel injection is effective to ensure combustion and ignition. As diesel fuel injection increases, HC concentration decreases, and NOx and CO concentration increases.

This research focused on the light emission behavior of the OH radical (characteristic spectrum of 306.4 nm) that plays a key role in combustion reactions, in order to investigate the influence of the residual gas on autoignition. The test engine used was a 2-stroke, air-cooled engine fitted with an exhaust pressure control valve in the exhaust manifold. When a certain level of internal EGR is forcibly applied, the temperature of the unburned end gas is raised on account of heat transfer from the hot residual gas and also due to compression by piston motion. As a result, the unburned end gas becomes active and autoignition tends to occur.

Lean burn gas engines are expected to reduce NOx emission while improving engine performances such as output and thermal efficiency. Recently, an ignition method using a small quantity of diesel fuel (pilot fuel) as an ignition source for lean-burn gas engines has introduced further improvement of their performance. Generally, this method has been used for pre-chamber engines because it could not successfully lead to reduce NOx and Particulate emissions when adopted for open-chamber engines. However, the possibility of improvement of performances of open-chamber engines with this ignition method has also been expected(1). An experimental study was conducted to investigate the performance of an open-chamber gas engine with pilot fuel for ignition source. Experiments were conducted by using a single cylinder gas engine equipped with a common-rail injection system.

The effect of external EGR on knock was evaluated using a CFR engine. Combustion pressure was sampled on a time basis. A band pass filter in the time domain was applied to the pressure cycles. Five knock indices were calculated for each combustion cycle. The problem to quantify knock intensity was focused. At this extent measurements were carried out on standard isooctane-n-heptane blends in the test conditions used for the determination of the Motor Method Octane Number (MON). Knock intensity was varied acting on compression ratio. For each index, the conditions of absence of knock were determined using motored cycles. The indices were compared and one of them, showing the lowest C.O.V., was selected for further measurements. The effect of EGR on test fuels having different composition was evaluated varying the compression ratio, at fixed ignition timing. In this way, the same level of detonation, obtained in the absence of EGR, was realized with different amount of external EGR.

Several knock-detection methods, based both on cylinder pressure analysis and on engine block vibration analysis, have been carefully scrutinized through a critical review of the knock-detection techniques available in literature. Issues have been discussed regarding the physical meaning of knock intensity measurement indexes, mechanical noise sensitivity, transducer type and location, filtering-frequency bands and crank-angle window selection. An experimental investigation has been carried out on a typical European mass-produced engine, and this has provided criteria for the selection of the most suitable and reliable techniques, and has allowed a comparison between experimental results obtained by means of different knock-detection methods.

Combustion information from three combustion chamber geometries was analyzed: Pancake and horseshoe geometry on a single-cylinder research engine, and pentroof geometry in a turbocharged four-cylinder production engine. Four different fuels were used. In the horseshoe configuration, the cylinder pressure traces from the burnt gas and from the end-gas pocket were evaluated. It is shown that the characteristics of knock are to a large degree a function of the combustion chamber geometry and that they are influenced strongly by the transducer position. It is shown for pentroof geometry that the number of cycles required to properly describe the knock population is a function of the knock intensity. A large error potential is shown for samples smaller than about 100 - 200 consecutive cycles. Good agreement between knock description based on accelerometer data and based on pressure data was found.

The work presented in this paper addresses the effects on combustion of recycling cooled exhaust gas (EGR) to the inlet charge of a standard production, four cylinder 2.3 l turbocharged, SI engine. The effect of various amounts of EGR at different temperatures and ignition timings were investigated. Considerable knock suppression at power output comparable with what was achieved with fuel enrichment, could be achieved by adding cooled EGR. Due to inherent high thermal loads, turbocharged engines have been operated at rich air/fuel-ratios during high load conditions, with subsequent high tailpipe emissions of CO in particular, but also HC. By substituting fuel enrichment with cooled EGR, a stoichiometric charge can be used, thus enabling the use of a three way catalytic converter at all operating conditions.