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Spark retard is desirable for decreasing cold start hydrocarbon emissions and lighting off the catalyst more rapidly. The focus of this work is to better understand the nature of the HC emissions as spark is retarded and investigate the location of the oxidation (in-cylinder or in the exhaust port and manifold). Fast FID measurements were taken in the exhaust port of a single cylinder research engine during cold, retarded spark engine operation (1200 rpm, 2.5 bar IMEP, 20 °C fluids). At moderate spark retard both Fast FID (exhaust port) and exhaust plenum HC levels decreased due to reduced crevice volume fraction at the end of burn, and increased in-cylinder burn up. In contrast, at large spark retard the port HC's increased dramatically while the exhaust plenum levels continued to fall to near zero. This is thought to be due to the onset of incomplete in-cylinder combustion along with increased exhaust port and manifold after-burning caused by the increasing exhaust gas temperatures.

The concentrations of individual exhaust hydrocarbon species were measured as a function of air-fuel ratio and EGR in a 2-liter four-cylinder engine using a gas chromatography, for natural gas and LPG. NMHC in addition to the species of HC, other emissions such as CO2, CO and NOx were at 1800rpm for two compression ratios (8.6 and 10.6) and various EGR ratios up to 7%. Fuel conversion efficiencies were also investigated together with emissions to study the effect of engine parameters on the combustion performances in gas engines especially under the lean burn conditions. It was found that CO2 emission decreased leaner mixture strength, the higher compression ratio and certainly with smaller C value of fuel. HC emissions from LPG engine consisted primarily of propane (larger 60%), ethylene and propylene, while main emissions from natural gas were methane (larger than 60%), ethane, ethylene and propane on the average.

One important design goal for spark-ignited engines is to minimize cyclic variability. A small amount of cyclic variability (slow burns) can produce undesirable engine vibrations. A larger amount of cyclic variability (incomplete burns) leads to increased hydrocarbon consumption/emissions. Recent studies have reported deterministic patterns in cyclic variability under extremely lean (misfiring) operating conditions. The present work is directed toward more realistic non-misfiring conditions. Production engine test results suggest that deterministic patterns in cyclic variability are the consequence of incomplete combustion, hence control algorithms based on the occurrence of these patterns are not expected to be of significant practical value.

Band spectrum images for CH, OH and CHO were taken in a heavy duty type LPG lean-burn SI engine, to investigate the combustion process as it pertains to the pollutant formation process in the post flame region. Full spectra and band spectrum flame images were observed with a bottom view single cylinder research engine and two high speed cameras. NOx emissions were also measured for excess air ratios ranging from 1.0 to 1.6. A thermodynamic model, including the detailed chemical kinetic mechanism for LPG and NOx formation reactions, was developed to predict the major reaction species in the post flame region, and NOx emissions during the combustion process. The model qualitatively described the flame images for each band spectrum and could predict the measured NOx emissions very well.

This paper proposes a concept of “lower temperature and higher pressure combustion” for natural gas engines in order to simultaneously achieve high performance, high reliability and low emissions. This concept should not only improve engine performance but also reduce engine thermal load (improve reliability) by adopting low engine speed specifications with the Miller cycle or EGR system while maintaining power output. This paper experimentally examines the effects of engine speed on performance, such as engine efficiency, friction loss, pump loss, heat loss, exhaust loss, blow-by loss, time loss, combustion efficiency, knock limit, combustion duration, combustion temperature and specific heat ratio.

One approach to the remediation of NOx generated under lean automotive engine conditions is its controlled storage and then periodic release and reaction under enriched conditions. This process is being considered for automotive exhaust systems that will be operated pre–dominantly lean for reasons of fuel economy. Because of the special characteristics of alkali and alkaline earth elements in the presence of NOx, they are being considered for use, in conjunction with γ–alumina–based washcoats and precious metal catalysts, as NOx catalyst coatings on cellular supports. It is known that alumino–silicates will react with alkali and alkaline earth elements to form stable ceramic phases when mixtures of the components are held in direct contact at elevated temperatures.

Influence of sulfur poisoning on NOx storage - reduction catalysts (NSR catalysts) was examined using both model gas and an actual vehicle. Deterioration of NSR catalysts is explained as the balance of sulfate formation in lean operating conditions and the amount of sulfate decomposed under rich operating conditions. This study focused on sulfate decomposition characteristics of NSR catalysts. First, sulfate decomposition characteristics of an NSR catalyst were examined in a model gas test. It was found that the initial temperature of SOx release was higher than the sulfur poisoning temperature. Crystal growth of sulfate by increasing temperature was assumed, and hence suppressed SOx release. Second, various sulfur concentrations (8 - 500 ppm) in gasoline were used for vehicle durability. The duration of one durability cycle was 1,260 seconds, including a 60 second regeneration of sulfur poisoning (AFR 14.2, 700 °C).

This paper charts the development of three three-way catalyst (TWC) and four lean-NOx trap (LNT) formulations in four vehicle systems over a four-year period. All LNTs were installed in an underbody location behind a close-coupled TWC on vehicles equipped with either port fuel injection (PFI) or direct injection spark ignition (DISI) engines. In addition to the standard regulatory European drive cycles, a series of steady-state tests were conducted to determine changes in LNT NOx efficiency with increasing NOx storage, and changes in the levels of individual nitrogen-containing exhaust components. Each vehicle system was subjected to a durability cycle up to an equivalent of 80,000 km. The early LNT formulations on systems ‘1’ and ‘2’ suffered from inadequate thermal durability with system efficiencies for NOx deteriorating to ≤ 55% after vehicle aging under lean operating drive cycle conditions (from ≥ 80% when fresh).

This paper describes a series of vehicle emission tests on a port-fuel injected lean-burn engine, to determine the preferred aftertreatment configuration yielding the most efficient regeneration of a lean-NOx trap (LNT). Three configurations were tested: (A) single starter three-way catalyst (TWC) upstream of an underfloor LNT; (B) bifurcated system with short downpipes comprising parallel TWCs upstream of a single underfloor LNT (Y-pipe configuration); and (C) bifurcated system with extended downpipes. System ‘A’ exhibits satisfactory LNT regeneration behaviour, and is within the European Stage III limits after accelerated aging. Results for system ‘B’, with identical TWC and LNT formulations as the single system, show that this LNT cannot be adequately regenerated under standard purge conditions; even with a fresh trap. In this non-optimized bifurcated system, the AFR profile entering the LNT during the rich purge deviates markedly from that requested by the calibration.

Sulphur poisoning and regeneration of NOx trap catalysts have been studied in synthetic exhausts and in an engine bench. Sulphur gradually poisoned the NOx storage sites in the axial direction of the NOx trap. During sulphur regenerations, hydrogen was found to be more efficient than carbon monoxide in removing the sulphur from the trap. The sulphur regeneration became more efficient the richer the environment (λ<1) and the higher the temperature (at least 600°C). H2S was found to be the main product during the sulphur regeneration. However, it was possible to reduce the H2S formation and instead produce more SO2 by running with lambda close to one or by pulsing lambda. Even if a relatively large amount of sulphur was removed from the NOx trap, these methods gave a much less efficient regeneration per sulphur atom removed than when running relatively rich constantly. Finally, a model that could explain this observation was proposed.

The behaviour of a NOx storage catalyst in powdered form and containing a storage component based on alkaline metal was investigated under rich conditions. Experiments were conducted in a fixed-bed flow reactor with the space velocity set at 45,000 h-1. From these experiments it was possible to extract the fractional NOx reduction and the efficiency of use of the reductant. With 0.9% CO as a reductant at 350°C, complete utilisation of CO was achieved up to 70% NOx conversion as treatment time was increased. To obtain 90% NOx conversion required longer times, and 23% of the CO did not participate in the reduction of NOX. A reductant balance shows that about 40% of the CO added is used to reduce the catalyst surface when the flow is switched from lean to rich. The ranking of efficiencies of different reductant gases at 350°C gave the following sequence: 0.9% H2 ≈ 0.9% CO > 1285 ppm toluene > 3000 ppm propene ≈ 1125 ppm i-octane > 3000 ppm propane.

The objective of the research presented in this paper, is to examine the potential to suppress knock and to reduce the exhaust gas temperature by using either lean mixtures or mixtures diluted with cooled EGR, at high load conditions, in a turbo charged spark ignited engine. Engine tests were carried out with lean mixtures, rich mixtures and mixtures diluted by cooled EGR at various degrees of dilution and at various inlet temperatures. The effects on the combustion process was evaluated at constant brake mean effective pressure for various levels of dilution at two different engine speeds. Full load performance was compared with the standard fuel enriched case. Both lean homogeneous operation and cooled EGR are possible replacements of fuel enrichment. Cooled EGR allows the use of a three-way catalytic converter at all operating conditions, resulting in substantially lower tailpipe emissions of CO and HC compared to rich operation.

For a NOx trap catalyst to work properly, it is important that the times for the lean period and the rich spikes are correctly calculated in the engine management system (EMS). This paper deals with the development of a physically based NOx trap model for implementation in the EMS. The catalyst was divided into different segments (complete mixed cells) to correctly mimic the axial distribution of stored NOx and the axial temperature profile. Furthermore, the model included physical steps as adsorption, desorption, storage and release of NOx. The model also includes the storage and reduction of O2 and a simplified model of the heat release from the oxidation of the reductants. The model could successfully describe the process of storage and release in a short time interval. However, problems to describe the function of the NOx trap occurred after longer time in the vehicle because of inaccurate estimation of the input variables.

In Germany 100.000 tons of biodiesel (rape seed oil methylester, RME) were produced in 1998. 200.000 tons are expected in 2000. Therefore, it is necessary to judge the environmental and health effects deriving from the use of RME in combustion engines. The analysis of particle size and particle number distributions of diesel soot and the determination of its mutagenic effect were investigated. Additionally, emissions of ozone precursors were analyzed for both fuels. Finally, regulated and some important non-regulated emissions from different blends of RME and fossil diesel fuel were determined.

Interest has been growing in many countries in the potential use of diesel particulate filters (DPF). This type of after treatment technology has been shown to make very significant reductions in both the mass of particulate emitted in diesel exhaust gas, and also in the number of fine particulates, which have been linked in recent years with concerns for human health. Work carried out during a development programme investigating the capability of fuel soluble metallic additives to assist DPF regeneration, indicated superior performance from a novel combination of metals in fuel soluble form. Earlier work showed that a fuel soluble combination of organo-metallic additives based on sodium and strontium gave very effective regeneration characteristics, and was capable of burning out carbon at temperatures from about 160°C.

To evaluate the performance of a variety of commercially available exhaust emission control technologies, the Manufacturers of Emission Controls Association (MECA) sponsored a test program at Southwest Research Institute (SwRI). The test engine was a current design heavy-duty diesel engine operated on standard No. 2 diesel (368 ppm) and lower sulfur (54 ppm) diesel fuel. Technologies evaluated included: diesel oxidation catalysts (DOCs), diesel particulate filters (DPFs), selective catalytic reduction (SCR), fuel-borne catalysts (FBCs) in combination with filters and oxidation catalysts, and combinations of the above technologies. The program was structured to demonstrate that a variety of exhaust emission control technologies, including exhaust gas recirculation, could be used to substantially reduce emissions from a modern MY 1998 heavy-duty diesel engine.

An advanced catalytic exhaust after-treatment system addresses the problem of NOX emissions from heavy-duty diesel trucks, relying on real-time catalyst modelling. The system consists of de-NOX catalysts, a device for injection of a reducing agent (diesel fuel) upstream the catalysts, and computer programmes to control the injection of the reducing agent and to model the engine and catalysts in real time. Experiments with 5 different air-assisted injectors were performed to determine the effect of injector design on the distribution of the injected diesel in the exhaust gas stream. A two-injector set-up was investigated to determine whether system efficiency could be increased without increasing the amount of catalyst or the amount of reducing agent necessary for the desired outcome. The results were verified by performing European standard transient cycle tests as well as stationary tests.

Various measurement techniques were employed to quantify sulfuric acid deposition levels and concentration of sulfuric acid in the condensate from the recirculated exhaust gas heat exchanger of a 1995 Cummins M11 heavy-duty diesel engine. Methods employed included a modified version of the sulfur species sampling system developed by Kreso et al. (1)*, rinsing the heat exchanger, and experiments employing a condensate collection device (CCD). The modified sampling system was applied to the inlet and outlet of the heat exchanger in order to quantify the changes in various sulfur compounds. Doped sulfur fuel (3300 to 4000 ppm S) was used to increase the concentrations of the various oxides of sulfur (SOx). These tests were performed at mode 9 of the old EPA 13-mode test cycle (1800 RPM, 932N*m) with 17-20% exhaust gas recirculation (EGR) at two EGR outlet temperatures: 160°C and 103°C.

Specific aspects of a study aimed at developing a microwave assisted regeneration system for diesel particulate traps are discussed. Results from thermal and microwave characteristic studies carried out in the initial phase of the study are reported. The critical parameters that need to be optimized, for achieving controlled regeneration, are microwave preheating time period, regenerative air supply, regenerative air temperature, and soot deposition. Using a 1000 W magnetron, power measurements were made to select the best waveguide configuration for optimized transmission. A six cylinder naturally aspirated, indirect injection diesel engine was retrofitted with a customized exhaust system that included a Corning EX80 (5.66″ × 6.00″) type ceramic particulate trap. An automated exhaust bypass system enabled trap loading and subsequent regeneration with a customized microwave regeneration system. The paper discusses the salient details of both on-line and off-line regeneration setups.

This paper describes an experimental study to determine the potential for fuel efficiency improvements offered by dedicated, high compression E85 engines with optimized powertrain calibration strategies. The study involved a prototype variable fuel engine that could operate using either gasoline or E85, and a high compression version of the same engine that was suitable only for E85. Fuel consumption and engine-out emissions were evaluated using steady-state engine dynamometer tests to represent urban and highway speed/load conditions. For each fuel and engine combination, the fuel efficiency and emissions trade-offs provided by varying Exhaust Gas Recirculation (EGR) levels were determined. For the high compression engine, operation at lower speed/higher load conditions (producing the same power as the standard speed/load settings) was also investigated.