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A new proportional collection system for extremely low tailpipe emission measurement in transient conditions has been developed. The new system can continuously sample a minute flow of exhaust gas, at a rate that is proportional to the engine exhaust rate. A zero grade gas dilution technique is utilized to prevent the influence of pollutants in atmospheric air that are the same concentration level as those in the exhaust gas. The system has accuracy within ±5%. For the direct exhaust gas flow meter, a pitot tube type flow meter is utilized as it is simple, heat resistant, sufficiently accurate and has low flow-resistance characteristic. For the collection and dilution controllers, two mass flow controllers (MFC) were adopted. The MFCs' output can be adversely influenced by variation of the specific heat of the sample gas, resulting in flow reporting error.

Due to increasing interest in the emissions-producing characteristics of today's automobiles, emissions testing procedures have come under close scrutiny. In addition, development of procedures to measure emissions of vehicles operating in “on-road” conditions have been proposed to gain knowledge of the instantaneous mass flow rates of various legislated gaseous emissions. The problem with the measurement of these instantaneous flow rates is that the responses of modern emissions analyzers to transients are too slow for reliable results. Therefore, a method for improving the dynamic response of these instruments is needed. A method is described which utilizes generalized predictive control theory concepts in conjunction with system identification techniques to produce a software “filter” which reconstructs the distorted output of these analyzers.

This paper explores the extent to which standard dilution tunnel measurements of motor vehicle exhaust particulate matter modify particle number and size. Steady state size distributions made directly at the tailpipe, using an ejector pump, are compared to dilution tunnel measurements for three configurations of transfer hose used to transport exhaust from the vehicle tailpipe to the dilution tunnel. For gasoline vehicles run at a steady 50 - 70 mph, ejector pump and dilution tunnel measurements give consistent results of particle size and number when using an uninsulated stainless steel transfer hose. Both methods show particles in the 10 - 100 nm range at tailpipe concentrations of the order of 104 particles/cm3.

The E-35 “Running Loss” program was planned in the fall of 1996, and conducted in the summer of 1997, as the third part of a series of Coordinating Research Council (CRC) sponsored evaporative emission test programs. One hundred and fifty vehicles (half cars - half light duty trucks) were recruited at a local I/M lane, and tested for running loss emissions at the ATL Facility in Mesa, AZ. The previous CRC programs had studied hot soak, and then diurnal emissions. Running loss emissions were measured in a Running Loss SHED (RL-SHED) for a 25 minute, 7.5 mile trip on a hot summer day (95°F). Vehicles from model years 1971 through 1991 were tested. A wide range in emission levels was observed - from a low of 0.13 g/mile to 43 g/mile. The test results were not able to establish whether car emissions are different, or the same, as light duty trucks. The major causes of the high emissions were liquid leaks on carburetor equipped models.

One hundred fifty-one vehicles were recruited from the I/M lane in Mesa, AZ during the summer of 1996, and their 24 hour diurnal emissions were measured in a variable temperature SHED (VT-SHED). The fleet selection included the earliest applications of evaporative emission control, and later technologies that had at least 5 years of exposure. Model years 1971 through 1991 were tested. Fifty-three percent of the sample tested had daily emissions of more than 10 grams. Five of the 151 were over 50 grams per day, and had significant liquid leaks. Twenty-six (17%) of the vehicles had emissions exceeding one gram per hour. Thirty-two of the 151 tested (21%) had identifiable liquid leaks. Carburetor systems had higher emissions than fuel injection systems. The highest emitters had resting losses of more than 0.8 g/hr. These eight highest emitters were considered outliers for the purposes of general analysis, and were not used, as is noted in the report.

The requirement to meet more stringent emission standards has focused attention on the effects of gasoline sulfur on automotive emissions. Numerous studies have shown that three-way catalyst performance is severely inhibited by sulfur. A literature review of laboratory studies on the interaction of sulfur with automotive catalyst components provides the basis for understanding impacts on catalyst activity under the variety of conditions encountered in vehicle operation. Under stoichiometric and rich conditions, SO2 formed during combustion is dissociatively adsorbed on platinum group metal surfaces to form strongly bound Sad. Sulfur inhibition results from both physical blockage and electronic effects of Sad, such that low coverage of Sad results in disproportionately higher levels of reaction site blockage. This is responsible for the nonlinear effects observed with increasing fuel sulfur level.

The oxidation of surrogate diesel fuels composed of mixtures of three pure hydrocarbons with and without their cetane numbers chemically enhanced using 2-ethylhexyl nitrate (2-EHN) is studied in a variable pressure flow reactor over a temperature range 500 - 900 K, at 12.5 atmospheres and a fixed reaction time of 1.8 sec. Changes in both low temperature, intermediate temperature, and hot ignition chemical kinetic behavior are noted with changes in the fuel cetane number. Differences appear in the product distribution and in heat release generated in the low and intermediate temperature regimes as cetane number is increased. A chemically enhanced cetane fuel shows nearly identical oxidation characteristics to those obtained using pure fuel blends to produce the enhanced cetane value. The decomposition chemistry of 2-EHN was also studied. Pyrolysis data of 10% 2-EHN in n-heptane and toluene are reported.

Government-industry partnerships are necessary for small businesses to successfully launch new and innovative ideas into the market place. Small businesses, the cornerstone for economic job creation, expansion and retention, is hampered with the need to fund new and innovative technologies from profits which generally occur in a cyclic manner. This cyclic funding leads to ramp ups and development during profitable years, and delays and abeyance during years of downturn. Government-industry partnerships directly addresses this problem by offering funding assistance in the form of resources eliminating the “peaks and valleys” of development. This paper will detail a case study of this type of assistance.

Through a cooperative effort with the U.S. Department of Energy (DOE) Office of Heavy Vehicle Technologies (OHVT), Alcoa is developing a casting process to produce ultra large thin wall components. The casting process is a low pressure, metal mold, multiport injection vertical casting process. The specific system for demonstration of the process is located at Alcoa's Technology Center and will be capable of producing parts extending 3 M long, 1.7 M wide and 0.4 M high. For example, single castings of car floor pan frames or side wall aperture structures are candidates for this installation. This shall provide a major opportunity to reduce the cost of lightweight transportation vehicle structures by (a) reducing the components or part count and (b) reducing the cost of assembly. To develop and demonstrate the process, an inner panel of the Chrysler minivan liftgate will be first produced on this system.

Thermal efficiencies of 54% have been demonstrated by single cylinder engine testing of advanced diesel engine concepts developed under Department of Energy funding. In order for these concept engines to be commercially viable, cost effective and durable systems for insulating the piston, head, ports and exhaust manifolds will be required. The application and development of new materials such as thick thermal barrier coating systems will be key to insulating these components. Development of test methods to rapidly evaluate the durability of coating systems without expensive engine testing is a major objective of current work. In addition, a novel, low cost method for producing thermal barrier coated pistons without final machining of the coating has been developed.

The objective of the Heavy Vehicle Propulsion Materials Program is to develop the enabling materials technology for the clean, high-efficiency diesel truck engines of the future. The development of cleaner, higher-efficiency diesel engines imposes greater mechanical, thermal, and tribological demands on materials of construction. Often the enabling technology for a new engine component is the material from which the part can be made. The Heavy Vehicle Propulsion Materials Program is a partnership between the Department of Energy (DOE), and the diesel engine companies in the United States, materials suppliers, national laboratories, and universities. A comprehensive research and development program has been developed to meet the enabling materials requirements for the diesel engines of the future.

The HTML (High Temperature Materials Laboratory) is a U.S. Department of Energy User Facility, offering opportunities for in-depth characterization of advanced materials, specializing in high-temperature-capable structural ceramics. Available are electron microscopy for micro-structural and microchemical analysis, equipment for measurement of the thermophysical and mechanical properties of ceramics to elevated temperatures, X-ray and neutron diffraction for structure and residual stress analysis, and high speed grinding machines with capability for measurement of component shape, tolerances, surface finish, and friction and wear properties. This presentation will focus on structural materials characterization, illustrated with examples of work performed on heat engine materials such as silicon nitride, industrial refractories, metal-and ceramic-matrix composites, and structural alloys.

This paper summarizes current work in the Environmental Science & Health Effects (ES&HE) Program being sponsored by DOE's Office of Heavy Vehicle Technologies (OHVT) through the National Renewable Energy Laboratory (NREL). The program is regulatory-driven, and focuses on ozone, airborne particles, visibility and regional haze, air toxics, and health effects of air pollutants. The goal of the ES&HE Program is to understand atmospheric impacts and potential health effects that may be caused by the use of petroleum-based and alternative transportation fuels. Each project in the program is designed to address policy-relevant objectives. Studies in the ES&HE Program have four areas of focus: improving technology for emissions measurements; vehicle emissions measurements, emission inventory development/improvement; and ambient impacts, including health effects.

The U.S. Department of Energy (DOE), Office of Heavy Vehicle Technologies (OHVT) is promoting the use of natural gas as a fuel option in the transportation energy sector through its natural gas vehicle program [1]. The goal of this program is to eliminate the technical and cost barriers associated with displacing imported petroleum. This is achieved by supporting research and development in technologies that reduce manufacturing costs, reduce emissions, and improve vehicle performance and consumer acceptance for natural gas fueled vehicles. In collaboration with Brookhaven National Laboratory, projects are currently being pursued in (1) liquefied natural gas production from unconventional sources, (2) onboard natural gas storage (adsorbent, compressed, and liquefied), (3) natural gas delivery systems for both onboard the vehicle and the refueling station, and (4) regional and enduse strategies.

The objectives of this paper are to describe the ongoing projects in diesel engine combustion research at Sandia National Laboratories' Combustion Research Facility and to detail recent experimental results. The approach we are employing is to assemble experimental hardware that mimic realistic engine geometries while enabling optical access. For example, we are using multi-cylinder engine heads or one-cylinder versions of production heads mated to one-cylinder engine blocks. Optical access is then obtained through a periscope in an exhaust valve, quartz windows in the piston crown, windows in spacer plates just below the head, or quartz cylinder liners. We have three diesel engine experiments supported by the Department of Energy, Office of Heavy Vehicle Technologies: a one-cylinder version of a Cummins heavy-duty engine, a diesel simulation facility, and a one-cylinder Caterpillar engine to evaluate combustion of alternative diesel fuels.

The DOE Office of Heavy Vehicle Technologies (OHVT) and its predecessor organizations have maintained aggressive projects in diesel exhaust aftertreatment since 1993. The Energy Policy Act of 1992, Section 2027, specifically authorized DOE to help accelerate the ability of U. S. diesel engine manufacturers to meet emissions regulations while maintaining the compression ignition engines inherently high efficiency. A variety of concepts and devices have been evaluated for NOx and Particulate matter (PM) control. Additionally, supporting technology in diagnostics for catalysis, PM measurement, and catalyst/reductant systems are being developed. This paper provides a summary of technologies that have been investigated and provides recent results from ongoing DOE-sponsored R&D. NOx control has been explored via active NOx catalysis, several plasma-assisted systems, electrochemical cells, and fuel additives.

To help guide heavy vehicle engine, fuel, and exhaust after-treatment technology development, the U.S. Department of Energy and the Lovelace Respiratory Research Institute are conducting research not addressed elsewhere on aspects of the toxicity of particulate engine emissions. Advances in these technologies that reduce diesel particulate mass emissions may result in changes in particle composition, and there is concern that the number of ultrafine (<0.1 micron) particles may increase. All present epidemiological and laboratory data on the toxicity of diesel emissions were derived from emissions of older-technology engines. New, short-term toxicity data are needed to make health-based choices among diesel technologies and to compare the toxicity of diesel emissions to those of other engine technologies.

Alternative compression ignition engine fuels are of interest both to reduce emissions and to reduce U.S. petroleum fuel demand. A Malaysian Fischer-Tropsch gas-to-liquid fuel was compared with California #2 diesel by characterizing emissions from over the road Class 8 tractors with Caterpillar 3176 engines, using a chassis dynamometer and full scale dilution tunnel. The 5-Mile route was employed as the test schedule, with a test weight of 42,000 lb. Levels of oxides of nitrogen (NOx) were reduced by an average of 12% and particulate matter (PM) by 25% for the Fischer-Tropsch fuel over the California diesel fuel. Another distillate fuel produced catalytically from Fischer-Tropsch products originally derived from natural gas by Mossgas was also compared with 49-state #2 diesel by characterizing emissions from Detroit Diesel 6V-92 powered transit buses, three of them equipped with catalytic converters and rebuilt engines, and three without.

In 1998, light trucks accounted for over 48% of new vehicle sales in the U.S. and well over half the new Light Duty vehicle fuel consumption. The Light Truck Clean Diesel (LTCD) program seeks to introduce large numbers of advanced technology diesel engines in light-duty trucks that would improve their fuel economy (mpg) by at least 50% and reduce our nation's dependence on foreign oil. Incorporating diesel engines in this application represents a high-risk technical and economic challenge.

Do older light trucks, often with second (and subsequent) owners, present a higher risk to either their own occupants or to other road users? And is the safety record for newer trucks better or worse than the record for their older counterparts? To answer these questions, fatalities in crashes involving at least one light truck were examined using the Fatal Analysis Reporting System (FARS). Fatality rates for both occupants of the light truck and for other road users (occupants of other motor vehicles, pedestrians, etc.) in these crashes were computed, based both on the number of registered vehicles and on the vehicle miles of travel. Two trends in these fatality rates are observed. First, as light trucks age, a consistent decline is found in risk both to their own occupants and to other road users. Second, a distinct decrease is found in road user risk for newer light trucks compared to older light trucks when they were new, both for their own occupants and for other road users.